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Photoinduced memory effect in a redox controllable bistable mechanical molecular switch.

Something to remember: A rotaxane could be operated as a bistable memory element under kinetic control (see picture). Data was written on the molecule by an oxidation stimulus and locked by UV light irradiation. After the writing session, the oxidized species was reduced back to the original form wi... Full description

Journal Title: Angewandte Chemie (International ed. in English) February 13, 2012, Vol.51(7), pp.1611-1615
Main Author: Avellini, Tommaso
Other Authors: Li, Hao , Coskun, Ali , Barin, Gokhan , Trabolsi, Ali , Basuray, Ashish N , Dey, Sanjeev K , Credi, Alberto , Silvi, Serena , Stoddart, J Fraser , Venturi, Margherita
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201107618
Link: http://search.proquest.com/docview/920366224/?pq-origsite=primo
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recordid: proquest920366224
title: Photoinduced memory effect in a redox controllable bistable mechanical molecular switch.
format: Article
creator:
  • Avellini, Tommaso
  • Li, Hao
  • Coskun, Ali
  • Barin, Gokhan
  • Trabolsi, Ali
  • Basuray, Ashish N
  • Dey, Sanjeev K
  • Credi, Alberto
  • Silvi, Serena
  • Stoddart, J Fraser
  • Venturi, Margherita
subjects:
  • Kinetics–Chemical Synthesis
  • Models, Molecular–Chemistry
  • Oxidation-Reduction–Chemistry
  • Photochemical Processes–Chemistry
  • Rotaxanes–Chemistry
  • Rotaxanes
ispartof: Angewandte Chemie (International ed. in English), February 13, 2012, Vol.51(7), pp.1611-1615
description: Something to remember: A rotaxane could be operated as a bistable memory element under kinetic control (see picture). Data was written on the molecule by an oxidation stimulus and locked by UV light irradiation. After the writing session, the oxidized species was reduced back to the original form without losing the written data for a few hours. Light irradiation also protects nonoxidized rotaxanes from accidental writing.
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 1521-3773 ; DOI: 10.1002/anie.201107618
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titlePhotoinduced memory effect in a redox controllable bistable mechanical molecular switch.
creatorAvellini, Tommaso ; Li, Hao ; Coskun, Ali ; Barin, Gokhan ; Trabolsi, Ali ; Basuray, Ashish N ; Dey, Sanjeev K ; Credi, Alberto ; Silvi, Serena ; Stoddart, J Fraser ; Venturi, Margherita
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descriptionSomething to remember: A rotaxane could be operated as a bistable memory element under kinetic control (see picture). Data was written on the molecule by an oxidation stimulus and locked by UV light irradiation. After the writing session, the oxidized species was reduced back to the original form without losing the written data for a few hours. Light irradiation also protects nonoxidized rotaxanes from accidental writing.
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titlePhotoinduced memory effect in a redox controllable bistable mechanical molecular switch.
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