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Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic.

A new bis(diphosphine) nickel(II) complex, [Ni(PPh2NR2)2](BF4)2, 1, (R = CH2CH2OCH3) is described. A ΔG{sup o} of 0.84 kcal/mol⁻¹ for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displays reversible electrocatalytic activity... Full description

Journal Title: Angewandte Chemie (International ed. in English) March 26, 2012, Vol.51(13), pp.3152-3155
Main Author: Smith, Stuart E
Other Authors: Yang, Jenny Y , Dubois, Daniel L , Bullock, R Morris
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201108461
Link: http://search.proquest.com/docview/934268564/?pq-origsite=primo
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title: Reversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic.
format: Article
creator:
  • Smith, Stuart E
  • Yang, Jenny Y
  • Dubois, Daniel L
  • Bullock, R Morris
subjects:
  • Biomimetic Materials–Chemistry
  • Catalysis–Chemistry
  • Coordination Complexes–Chemistry
  • Hydrogen–Chemistry
  • Hydrogenase–Chemistry
  • Nickel–Chemistry
  • Oxidation-Reduction–Chemistry
  • Phosphines–Chemistry
  • Thermodynamics–Chemistry
  • Coordination Complexes
  • Phosphines
  • Nickel
  • Hydrogen
  • Hydrogenase
  • Phosphine
ispartof: Angewandte Chemie (International ed. in English), March 26, 2012, Vol.51(13), pp.3152-3155
description: A new bis(diphosphine) nickel(II) complex, [Ni(PPh2NR2)2](BF4)2, 1, (R = CH2CH2OCH3) is described. A ΔG{sup o} of 0.84 kcal/mol⁻¹ for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displays reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, a characteristic most commonly associated with hydrogenase enzymes. Journal Article.
language: eng
source:
identifier: E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201108461
fulltext: fulltext
issn:
  • 15213773
  • 1521-3773
url: Link


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titleReversible electrocatalytic production and oxidation of hydrogen at low overpotentials by a functional hydrogenase mimic.
creatorSmith, Stuart E ; Yang, Jenny Y ; Dubois, Daniel L ; Bullock, R Morris
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identifierE-ISSN: 1521-3773 ; DOI: 10.1002/anie.201108461
subjectBiomimetic Materials–Chemistry ; Catalysis–Chemistry ; Coordination Complexes–Chemistry ; Hydrogen–Chemistry ; Hydrogenase–Chemistry ; Nickel–Chemistry ; Oxidation-Reduction–Chemistry ; Phosphines–Chemistry ; Thermodynamics–Chemistry ; Coordination Complexes ; Phosphines ; Nickel ; Hydrogen ; Hydrogenase ; Phosphine
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descriptionA new bis(diphosphine) nickel(II) complex, [Ni(PPh2NR2)2](BF4)2, 1, (R = CH2CH2OCH3) is described. A ΔG{sup o} of 0.84 kcal/mol⁻¹ for hydrogen addition for this complex was calculated from the experimentally determined equilibrium constant. This complex displays reversible electrocatalytic activity for hydrogen production and oxidation at low overpotentials, a characteristic most commonly associated with hydrogenase enzymes. Journal Article.
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