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Enantioselective aza-Michael reaction of hydrazide to chalcones through the nonactivated amine moiety conjugated addition

The catalytic asymmetric aza-Michael reaction of benzoyl hydrazine toward chalcones through the nonactivated amine moiety conjugated addition was facilitated by the developed N,N-dioxide-Sc(OTf)3 complex under mild conditions, affording the pharmacologically and synthetically useful products in mode... Full description

Journal Title: Chemical Communications 2011, Vol.47(13), pp.4016-4018
Main Author: Jiang, Jun
Other Authors: Cai, Yunfei , Chen, Weiliang , Lin, Lili , Liu, Xiaohua , Feng, Xiaoming
Format: Electronic Article Electronic Article
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ID: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c0cc05804a
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recordid: rscc0cc05804a
title: Enantioselective aza-Michael reaction of hydrazide to chalcones through the nonactivated amine moiety conjugated addition
format: Article
creator:
  • Jiang, Jun
  • Cai, Yunfei
  • Chen, Weiliang
  • Lin, Lili
  • Liu, Xiaohua
  • Feng, Xiaoming
subjects:
  • Chemistry
ispartof: Chemical Communications, 2011, Vol.47(13), pp.4016-4018
description: The catalytic asymmetric aza-Michael reaction of benzoyl hydrazine toward chalcones through the nonactivated amine moiety conjugated addition was facilitated by the developed N,N-dioxide-Sc(OTf)3 complex under mild conditions, affording the pharmacologically and synthetically useful products in moderate to high yields with up to 97% ee.
language:
source:
identifier: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c0cc05804a
fulltext: fulltext
issn:
  • 1359-7345
  • 1364-548X
  • 1364548X
  • 13597345
url: Link


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titleEnantioselective aza-Michael reaction of hydrazide to chalcones through the nonactivated amine moiety conjugated addition
creatorJiang, Jun ; Cai, Yunfei ; Chen, Weiliang ; Lin, Lili ; Liu, Xiaohua ; Feng, Xiaoming
ispartofChemical Communications, 2011, Vol.47(13), pp.4016-4018
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descriptionThe catalytic asymmetric aza-Michael reaction of benzoyl hydrazine toward chalcones through the nonactivated amine moiety conjugated addition was facilitated by the developed N,N-dioxide-Sc(OTf)3 complex under mild conditions, affording the pharmacologically and synthetically useful products in moderate to high yields with up to 97% ee.
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titleEnantioselective aza-Michael reaction of hydrazide to chalcones through the nonactivated amine moiety conjugated addition
descriptionThe catalytic asymmetric aza-Michael reaction of benzoyl hydrazine toward chalcones through the nonactivated amine moiety conjugated addition was facilitated by the developed N,N-dioxide-Sc(OTf)3 complex under mild conditions, affording the pharmacologically and synthetically useful products in moderate to high yields with up to 97% ee.
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titleEnantioselective aza-Michael reaction of hydrazide to chalcones through the nonactivated amine moiety conjugated addition
authorJiang, Jun ; Cai, Yunfei ; Chen, Weiliang ; Lin, Lili ; Liu, Xiaohua ; Feng, Xiaoming
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abstractThe catalytic asymmetric aza-Michael reaction of benzoyl hydrazine toward chalcones through the nonactivated amine moiety conjugated addition was facilitated by the developed N,N-dioxide-Sc(OTf)3 complex under mild conditions, affording the pharmacologically and synthetically useful products in moderate to high yields with up to 97% ee.
doi10.1039/c0cc05804a
pages4016-408
date2011-03-15