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Interior aliphatic CH bond activation on iron( ii ) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation

Iron oxidation, in conjunction with NO coordination, achieved a CH bond activation to convert [Fe II ( H CTPP CH 3 )Br] into [Fe( H CTPP CH 2 )(NO)](BF 4 ) at ambient temperature. The structural data and theoretical calculations confirmed the role of nitric oxide behaving as a -accepting ligand to a... Full description

Journal Title: Chemical Communications 2012, Vol.48(41), pp.4989-4991
Main Author: Ching, Wei-min
Other Authors: Hung, Chen-hsiung
Format: Electronic Article Electronic Article
Language:
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ID: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c2cc31053h
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recordid: rscc2cc31053h
title: Interior aliphatic CH bond activation on iron( ii ) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation
format: Article
creator:
  • Ching, Wei-min
  • Hung, Chen-hsiung
subjects:
  • Activation
  • Ambient Temperature
  • Bonding
  • Iron
  • Ligands
  • Mathematical Analysis
  • Nitric Oxide
  • Oxidation
  • Miscellaneous Sciences (So)
  • Components and Materials (General) (Ea)
ispartof: Chemical Communications, 2012, Vol.48(41), pp.4989-4991
description: Iron oxidation, in conjunction with NO coordination, achieved a CH bond activation to convert [Fe II ( H CTPP CH 3 )Br] into [Fe( H CTPP CH 2 )(NO)](BF 4 ) at ambient temperature. The structural data and theoretical calculations confirmed the role of nitric oxide behaving as a -accepting ligand to assist the CH bond activation.
language:
source:
identifier: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c2cc31053h
fulltext: fulltext
issn:
  • 1359-7345
  • 1364-548X
  • 1364548X
  • 13597345
url: Link


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titleInterior aliphatic CH bond activation on iron( ii ) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation
creatorChing, Wei-min ; Hung, Chen-hsiung
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descriptionIron oxidation, in conjunction with NO coordination, achieved a CH bond activation to convert [Fe II ( H CTPP CH 3 )Br] into [Fe( H CTPP CH 2 )(NO)](BF 4 ) at ambient temperature. The structural data and theoretical calculations confirmed the role of nitric oxide behaving as a -accepting ligand to assist the CH bond activation.
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subjectActivation ; Ambient Temperature ; Bonding ; Iron ; Ligands ; Mathematical Analysis ; Nitric Oxide ; Oxidation ; Miscellaneous Sciences (So) ; Components and Materials (General) (Ea);
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titleInterior aliphatic CH bond activation on iron( ii ) N-confused porphyrin through synergistic nitric oxide binding and iron oxidation
descriptionIron oxidation, in conjunction with NO coordination, achieved a CH bond activation to convert [Fe II ( H CTPP CH 3 )Br] into [Fe( H CTPP CH 2 )(NO)](BF 4 ) at ambient temperature. The structural data and theoretical calculations confirmed the role of nitric oxide behaving as a -accepting ligand to assist the CH bond activation.
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abstractIron oxidation, in conjunction with NO coordination, achieved a CH bond activation to convert [Fe II ( H CTPP CH 3 )Br] into [Fe( H CTPP CH 2 )(NO)](BF 4 ) at ambient temperature. The structural data and theoretical calculations confirmed the role of nitric oxide behaving as a -accepting ligand to assist the CH bond activation.
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