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Enantioselective FriedelCrafts reactions between phenols and N -tosylaldimines catalyzed by a leucine-derived bifunctional catalyst

Enantioselective FriedelCrafts reactions between phenols and N -tosylaldimines were developed using a bifunctional catalyst readily prepared from l -leucine. The chiral benzylic amine products were obtained in high yields (up to 96% yield) and good to high enantiomeric excesses (up to 95% ee).

Journal Title: Chemical Communications 2012, Vol.48(44), pp.5518-5520
Main Author: Li, Guo-xing
Other Authors: Qu, Jin
Format: Electronic Article Electronic Article
Language:
Subjects:
ID: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c2cc31735d
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recordid: rscc2cc31735d
title: Enantioselective FriedelCrafts reactions between phenols and N -tosylaldimines catalyzed by a leucine-derived bifunctional catalyst
format: Article
creator:
  • Li, Guo-xing
  • Qu, Jin
subjects:
  • Benzylamines -- Chemical Synthesis
  • Imines -- Chemistry
  • Leucine -- Chemistry
  • Phenols -- Chemistry
  • Tosyl Compounds -- Chemistry
ispartof: Chemical Communications, 2012, Vol.48(44), pp.5518-5520
description: Enantioselective FriedelCrafts reactions between phenols and N -tosylaldimines were developed using a bifunctional catalyst readily prepared from l -leucine. The chiral benzylic amine products were obtained in high yields (up to 96% yield) and good to high enantiomeric excesses (up to 95% ee).
language:
source:
identifier: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c2cc31735d
fulltext: fulltext
issn:
  • 1359-7345
  • 1364-548X
  • 1364548X
  • 13597345
url: Link


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titleEnantioselective FriedelCrafts reactions between phenols and N -tosylaldimines catalyzed by a leucine-derived bifunctional catalyst
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ispartofChemical Communications, 2012, Vol.48(44), pp.5518-5520
identifier
descriptionEnantioselective FriedelCrafts reactions between phenols and N -tosylaldimines were developed using a bifunctional catalyst readily prepared from l -leucine. The chiral benzylic amine products were obtained in high yields (up to 96% yield) and good to high enantiomeric excesses (up to 95% ee).
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subjectBenzylamines -- Chemical Synthesis ; Imines -- Chemistry ; Leucine -- Chemistry ; Phenols -- Chemistry ; Tosyl Compounds -- Chemistry;
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titleEnantioselective FriedelCrafts reactions between phenols and N -tosylaldimines catalyzed by a leucine-derived bifunctional catalyst
descriptionEnantioselective FriedelCrafts reactions between phenols and N -tosylaldimines were developed using a bifunctional catalyst readily prepared from l -leucine. The chiral benzylic amine products were obtained in high yields (up to 96% yield) and good to high enantiomeric excesses (up to 95% ee).
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authorLi, Guo-xing ; Qu, Jin
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abstractEnantioselective FriedelCrafts reactions between phenols and N -tosylaldimines were developed using a bifunctional catalyst readily prepared from l -leucine. The chiral benzylic amine products were obtained in high yields (up to 96% yield) and good to high enantiomeric excesses (up to 95% ee).
doi10.1039/c2cc31735d
pages5518-5520
date2012-05-07