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Metal-free oxidative hydroxyalkylarylation of activated alkenes by direct sp 3 CH functionalization of alcohols

A metal-free tandem radical addition/cyclization reaction of activated alkenes and alcohols has been developed. The process provides an efficient and atom economical access to various valuable hydroxyl-containing oxindoles through the direct sp 3 CH functionalization of alcohols.

Journal Title: Chemical Communications 2013, Vol.49(68), pp.7540-7542
Main Author: Meng, Yuan
Other Authors: Guo, Li-na , Wang, Hua , Duan, Xin-hua
Format: Electronic Article Electronic Article
Language:
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ID: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c3cc44055a
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recordid: rscc3cc44055a
title: Metal-free oxidative hydroxyalkylarylation of activated alkenes by direct sp 3 CH functionalization of alcohols
format: Article
creator:
  • Meng, Yuan
  • Guo, Li-na
  • Wang, Hua
  • Duan, Xin-hua
subjects:
  • Alcohols
  • Economics
  • Alkenes
  • Activated
  • Radicals
  • Miscellaneous Sciences (So)
  • Components and Materials (General) (Ea)
ispartof: Chemical Communications, 2013, Vol.49(68), pp.7540-7542
description: A metal-free tandem radical addition/cyclization reaction of activated alkenes and alcohols has been developed. The process provides an efficient and atom economical access to various valuable hydroxyl-containing oxindoles through the direct sp 3 CH functionalization of alcohols.
language:
source:
identifier: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c3cc44055a
fulltext: fulltext
issn:
  • 1359-7345
  • 1364-548X
  • 1364548X
  • 13597345
url: Link


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titleMetal-free oxidative hydroxyalkylarylation of activated alkenes by direct sp 3 CH functionalization of alcohols
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descriptionA metal-free tandem radical addition/cyclization reaction of activated alkenes and alcohols has been developed. The process provides an efficient and atom economical access to various valuable hydroxyl-containing oxindoles through the direct sp 3 CH functionalization of alcohols.
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subjectAlcohols ; Economics ; Alkenes ; Activated ; Radicals ; Miscellaneous Sciences (So) ; Components and Materials (General) (Ea);
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titleMetal-free oxidative hydroxyalkylarylation of activated alkenes by direct sp 3 CH functionalization of alcohols
descriptionA metal-free tandem radical addition/cyclization reaction of activated alkenes and alcohols has been developed. The process provides an efficient and atom economical access to various valuable hydroxyl-containing oxindoles through the direct sp 3 CH functionalization of alcohols.
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titleMetal-free oxidative hydroxyalkylarylation of activated alkenes by direct sp 3 CH functionalization of alcohols
authorMeng, Yuan ; Guo, Li-na ; Wang, Hua ; Duan, Xin-hua
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abstractA metal-free tandem radical addition/cyclization reaction of activated alkenes and alcohols has been developed. The process provides an efficient and atom economical access to various valuable hydroxyl-containing oxindoles through the direct sp 3 CH functionalization of alcohols.
doi10.1039/c3cc44055a
pages7540-7542
date2013-07-30