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A highly porous NbO type metalorganic framework constructed from an expanded tetracarboxylate

A novel NbO type microporous metalorganic framework Cu 2 L ( ZJU-32 ; H 4 L = 5-((3,5-dicarboxyphenyl)ethynyl)-[1,1:3,1-terphenyl]-4,4-dicarboxylic acid) constructed from an elaborately designed tetratopic ligand was solvothermally synthesized and structurally characterized. The activated ZJU-32a ex... Full description

Journal Title: Chemical Communications 2014, Vol.50(13), pp.1552-1554
Main Author: Cai, Jianfeng
Other Authors: Rao, Xingtang , He, Yabing , Yu, Jancan , Wu, Chuande , Zhou, Wei , Yildirim, Taner , Chen, Banglin , Qian, Guodong
Format: Electronic Article Electronic Article
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ID: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c3cc48747d
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recordid: rscc3cc48747d
title: A highly porous NbO type metalorganic framework constructed from an expanded tetracarboxylate
format: Article
creator:
  • Cai, Jianfeng
  • Rao, Xingtang
  • He, Yabing
  • Yu, Jancan
  • Wu, Chuande
  • Zhou, Wei
  • Yildirim, Taner
  • Chen, Banglin
  • Qian, Guodong
subjects:
  • Carboxylic Acids -- Chemistry
  • Niobium -- Chemistry
  • Organometallic Compounds -- Chemistry
  • Oxides -- Chemistry
ispartof: Chemical Communications, 2014, Vol.50(13), pp.1552-1554
description: A novel NbO type microporous metalorganic framework Cu 2 L ( ZJU-32 ; H 4 L = 5-((3,5-dicarboxyphenyl)ethynyl)-[1,1:3,1-terphenyl]-4,4-dicarboxylic acid) constructed from an elaborately designed tetratopic ligand was solvothermally synthesized and structurally characterized. The activated ZJU-32a exhibits high permanent porosity with the BrunauerEmmettTeller (BET) surface area of 3831 m 2 g 1 and the pore volume of 1.482 cm 3 g 1 , enabling it to be a promising material for both methane storage and carbon dioxide capture at room temperature.
language:
source:
identifier: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c3cc48747d
fulltext: fulltext
issn:
  • 1359-7345
  • 1364-548X
  • 1364548X
  • 13597345
url: Link


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titleA highly porous NbO type metalorganic framework constructed from an expanded tetracarboxylate
creatorCai, Jianfeng ; Rao, Xingtang ; He, Yabing ; Yu, Jancan ; Wu, Chuande ; Zhou, Wei ; Yildirim, Taner ; Chen, Banglin ; Qian, Guodong
ispartofChemical Communications, 2014, Vol.50(13), pp.1552-1554
identifier
descriptionA novel NbO type microporous metalorganic framework Cu 2 L ( ZJU-32 ; H 4 L = 5-((3,5-dicarboxyphenyl)ethynyl)-[1,1:3,1-terphenyl]-4,4-dicarboxylic acid) constructed from an elaborately designed tetratopic ligand was solvothermally synthesized and structurally characterized. The activated ZJU-32a exhibits high permanent porosity with the BrunauerEmmettTeller (BET) surface area of 3831 m 2 g 1 and the pore volume of 1.482 cm 3 g 1 , enabling it to be a promising material for both methane storage and carbon dioxide capture at room temperature.
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subjectCarboxylic Acids -- Chemistry ; Niobium -- Chemistry ; Organometallic Compounds -- Chemistry ; Oxides -- Chemistry;
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titleA highly porous NbO type metalorganic framework constructed from an expanded tetracarboxylate
descriptionA novel NbO type microporous metalorganic framework Cu 2 L ( ZJU-32 ; H 4 L = 5-((3,5-dicarboxyphenyl)ethynyl)-[1,1:3,1-terphenyl]-4,4-dicarboxylic acid) constructed from an elaborately designed tetratopic ligand was solvothermally synthesized and structurally characterized. The activated ZJU-32a exhibits high permanent porosity with the BrunauerEmmettTeller (BET) surface area of 3831 m 2 g 1 and the pore volume of 1.482 cm 3 g 1 , enabling it to be a promising material for both methane storage and carbon dioxide capture at room temperature.
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titleA highly porous NbO type metalorganic framework constructed from an expanded tetracarboxylate
authorCai, Jianfeng ; Rao, Xingtang ; He, Yabing ; Yu, Jancan ; Wu, Chuande ; Zhou, Wei ; Yildirim, Taner ; Chen, Banglin ; Qian, Guodong
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abstractA novel NbO type microporous metalorganic framework Cu 2 L ( ZJU-32 ; H 4 L = 5-((3,5-dicarboxyphenyl)ethynyl)-[1,1:3,1-terphenyl]-4,4-dicarboxylic acid) constructed from an elaborately designed tetratopic ligand was solvothermally synthesized and structurally characterized. The activated ZJU-32a exhibits high permanent porosity with the BrunauerEmmettTeller (BET) surface area of 3831 m 2 g 1 and the pore volume of 1.482 cm 3 g 1 , enabling it to be a promising material for both methane storage and carbon dioxide capture at room temperature.
doi10.1039/c3cc48747d
pages1552-1554
date2014-01-16