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New methods for the synthesis of naphthyl amines; application to the synthesis of dihydrosanguinarine, sanguinarine, oxysanguinarine and ()-maclekarpines B and C

A new method for preparing naphthyl amines from 1,5 unsaturated dicarbonyl precursors is described; the utility of this new method was proven in the syntheses of several natural products, all containing the benzo[ c ]phenanthridine core and enabled by a radical promoted cyclisation of the naphthyl a... Full description

Journal Title: Chemical Communications 2014, Vol.50(77), pp.11314-11316
Main Author: Tatton, Matthew R.
Other Authors: Simpson, Iain , Donohoe, Timothy J.
Format: Electronic Article Electronic Article
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Subjects:
ID: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c4cc05209a
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recordid: rscc4cc05209a
title: New methods for the synthesis of naphthyl amines; application to the synthesis of dihydrosanguinarine, sanguinarine, oxysanguinarine and ()-maclekarpines B and C
format: Article
creator:
  • Tatton, Matthew R.
  • Simpson, Iain
  • Donohoe, Timothy J.
subjects:
  • Amines -- Chemical Synthesis
  • Benzodioxoles -- Chemical Synthesis
  • Benzophenanthridines -- Chemical Synthesis
ispartof: Chemical Communications, 2014, Vol.50(77), pp.11314-11316
description: A new method for preparing naphthyl amines from 1,5 unsaturated dicarbonyl precursors is described; the utility of this new method was proven in the syntheses of several natural products, all containing the benzo[ c ]phenanthridine core and enabled by a radical promoted cyclisation of the naphthyl amine products formed in the key cyclisation.
language:
source:
identifier: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c4cc05209a
fulltext: fulltext
issn:
  • 1359-7345
  • 1364-548X
  • 1364548X
  • 13597345
url: Link


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titleNew methods for the synthesis of naphthyl amines; application to the synthesis of dihydrosanguinarine, sanguinarine, oxysanguinarine and ()-maclekarpines B and C
creatorTatton, Matthew R. ; Simpson, Iain ; Donohoe, Timothy J.
ispartofChemical Communications, 2014, Vol.50(77), pp.11314-11316
identifier
descriptionA new method for preparing naphthyl amines from 1,5 unsaturated dicarbonyl precursors is described; the utility of this new method was proven in the syntheses of several natural products, all containing the benzo[ c ]phenanthridine core and enabled by a radical promoted cyclisation of the naphthyl amine products formed in the key cyclisation.
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subjectAmines -- Chemical Synthesis ; Benzodioxoles -- Chemical Synthesis ; Benzophenanthridines -- Chemical Synthesis;
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titleNew methods for the synthesis of naphthyl amines; application to the synthesis of dihydrosanguinarine, sanguinarine, oxysanguinarine and ()-maclekarpines B and C
descriptionA new method for preparing naphthyl amines from 1,5 unsaturated dicarbonyl precursors is described; the utility of this new method was proven in the syntheses of several natural products, all containing the benzo[ c ]phenanthridine core and enabled by a radical promoted cyclisation of the naphthyl amine products formed in the key cyclisation.
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titleNew methods for the synthesis of naphthyl amines; application to the synthesis of dihydrosanguinarine, sanguinarine, oxysanguinarine and ()-maclekarpines B and C
authorTatton, Matthew R. ; Simpson, Iain ; Donohoe, Timothy J.
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atitleNew methods for the synthesis of naphthyl amines; application to the synthesis of dihydrosanguinarine, sanguinarine, oxysanguinarine and ()-maclekarpines B and C
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abstractA new method for preparing naphthyl amines from 1,5 unsaturated dicarbonyl precursors is described; the utility of this new method was proven in the syntheses of several natural products, all containing the benzo[ c ]phenanthridine core and enabled by a radical promoted cyclisation of the naphthyl amine products formed in the key cyclisation.
doi10.1039/c4cc05209a
pages11314-11316
date2014-08-28