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The various architectures and properties of a series of coordination polymers tuned by the central metals

Five new metalorganic coordination polymers based on the mixed ligands of a semi-rigid bis-pyridyl-bis-amide N , N -bis(3-pyridinecarboxamide)-1,2-cyclohexane (3-bpah) and 1,4-benzenedicarboxylic acid (1,4-H 2 BDC), namely [Co(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 1 ), [Ni(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 2 ),... Full description

Journal Title: Dalton Transactions Dalton Transactions, 2014, Vol.43(21), pp.8072-8082
Main Author: Wang, Xiu-Li
Other Authors: Luan, Jian , Lin, Hong-Yan , Le, Mao , Liu, Guo-Cheng
Format: Electronic Article Electronic Article
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ID: ISSN: 1477-9237 ; E-ISSN: 1477-9245 ; DOI: 10.1039/c4dt00064a
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recordid: rscc4dt00064a
title: The various architectures and properties of a series of coordination polymers tuned by the central metals
format: Article
creator:
  • Wang, Xiu-Li
  • Luan, Jian
  • Lin, Hong-Yan
  • Le, Mao
  • Liu, Guo-Cheng
subjects:
  • Three Dimensional
  • Ethyl Alcohol
  • Topology
  • Architecture
  • Supramolecular Frameworks
  • Coordination Polymers
  • Ligands
  • Ethanol
  • Miscellaneous Sciences (So)
  • General and Nonclassified (Ep)
  • General and Nonclassified (Ed)
  • General and Nonclassified (EC)
ispartof: Dalton Transactions, Dalton Transactions, 2014, Vol.43(21), pp.8072-8082
description: Five new metalorganic coordination polymers based on the mixed ligands of a semi-rigid bis-pyridyl-bis-amide N , N -bis(3-pyridinecarboxamide)-1,2-cyclohexane (3-bpah) and 1,4-benzenedicarboxylic acid (1,4-H 2 BDC), namely [Co(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 1 ), [Ni(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 2 ), [Cu(3-bpah)(1,4-BDC)] ( 3 ), [Zn(3-bpah)(1,4-BDC)]H 2 O ( 4 ) and [Cd(3-bpah)(1,4-BDC)(H 2 O)] ( 5 ), have been hydrothermally synthesized and structurally characterized. Complexes 1 and 2 are isostructural and display the similar 1D infinite chains, which are further linked via hydrogen-bonding interactions to generate 3D supramolecular frameworks. Complex 3 features a 3D polymeric framework with CdSO 4 -like topology. Complexes 4 and 5 show two similar 2D (2,4)-connected networks with (48 5 )(4) topology, in which the 3-bpah ligands adopt different 2 -bridging coordination modes via the ligation of two pyridyl nitrogen atoms in 4 and via the ligation of one pyridyl nitrogen and one amide oxygen atom in 5 . In addition, the central metals show different coordination geometries in 4 and 5 . The adjacent layers of complexes 4 and 5 are finally extended into 3D supramolecular architectures through hydrogen-bonding interactions. The effects of the central metals on the structures and properties of complexes 15 have been discussed. The electrochemical properties of complexes 13 and fluorescent sensing behaviors of 45 toward ethanol and nitrobenzene have been investigated in detail.
language:
source:
identifier: ISSN: 1477-9237 ; E-ISSN: 1477-9245 ; DOI: 10.1039/c4dt00064a
fulltext: fulltext
issn:
  • 1477-9226
  • 1477-9234
  • 14779234
  • 14779226
url: Link


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titleThe various architectures and properties of a series of coordination polymers tuned by the central metals
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descriptionFive new metalorganic coordination polymers based on the mixed ligands of a semi-rigid bis-pyridyl-bis-amide N , N -bis(3-pyridinecarboxamide)-1,2-cyclohexane (3-bpah) and 1,4-benzenedicarboxylic acid (1,4-H 2 BDC), namely [Co(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 1 ), [Ni(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 2 ), [Cu(3-bpah)(1,4-BDC)] ( 3 ), [Zn(3-bpah)(1,4-BDC)]H 2 O ( 4 ) and [Cd(3-bpah)(1,4-BDC)(H 2 O)] ( 5 ), have been hydrothermally synthesized and structurally characterized. Complexes 1 and 2 are isostructural and display the similar 1D infinite chains, which are further linked via hydrogen-bonding interactions to generate 3D supramolecular frameworks. Complex 3 features a 3D polymeric framework with CdSO 4 -like topology. Complexes 4 and 5 show two similar 2D (2,4)-connected networks with (48 5 )(4) topology, in which the 3-bpah ligands adopt different 2 -bridging coordination modes via the ligation of two pyridyl nitrogen atoms in 4 and via the ligation of one pyridyl nitrogen and one amide oxygen atom in 5 . In addition, the central metals show different coordination geometries in 4 and 5 . The adjacent layers of complexes 4 and 5 are finally extended into 3D supramolecular architectures through hydrogen-bonding interactions. The effects of the central metals on the structures and properties of complexes 15 have been discussed. The electrochemical properties of complexes 13 and fluorescent sensing behaviors of 45 toward ethanol and nitrobenzene have been investigated in detail.
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subjectThree Dimensional ; Ethyl Alcohol ; Topology ; Architecture ; Supramolecular Frameworks ; Coordination Polymers ; Ligands ; Ethanol ; Miscellaneous Sciences (So) ; General and Nonclassified (Ep) ; General and Nonclassified (Ed) ; General and Nonclassified (EC);
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titleThe various architectures and properties of a series of coordination polymers tuned by the central metals
descriptionFive new metalorganic coordination polymers based on the mixed ligands of a semi-rigid bis-pyridyl-bis-amide N , N -bis(3-pyridinecarboxamide)-1,2-cyclohexane (3-bpah) and 1,4-benzenedicarboxylic acid (1,4-H 2 BDC), namely [Co(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 1 ), [Ni(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 2 ), [Cu(3-bpah)(1,4-BDC)] ( 3 ), [Zn(3-bpah)(1,4-BDC)]H 2 O ( 4 ) and [Cd(3-bpah)(1,4-BDC)(H 2 O)] ( 5 ), have been hydrothermally synthesized and structurally characterized. Complexes 1 and 2 are isostructural and display the similar 1D infinite chains, which are further linked via hydrogen-bonding interactions to generate 3D supramolecular frameworks. Complex 3 features a 3D polymeric framework with CdSO 4 -like topology. Complexes 4 and 5 show two similar 2D (2,4)-connected networks with (48 5 )(4) topology, in which the 3-bpah ligands adopt different 2 -bridging coordination modes via the ligation of two pyridyl nitrogen atoms in 4 and via the ligation of one pyridyl nitrogen and one amide oxygen atom in 5 . In addition, the central metals show different coordination geometries in 4 and 5 . The adjacent layers of complexes 4 and 5 are finally extended into 3D supramolecular architectures through hydrogen-bonding interactions. The effects of the central metals on the structures and properties of complexes 15 have been discussed. The electrochemical properties of complexes 13 and fluorescent sensing behaviors of 45 toward ethanol and nitrobenzene have been investigated in detail.
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abstractFive new metalorganic coordination polymers based on the mixed ligands of a semi-rigid bis-pyridyl-bis-amide N , N -bis(3-pyridinecarboxamide)-1,2-cyclohexane (3-bpah) and 1,4-benzenedicarboxylic acid (1,4-H 2 BDC), namely [Co(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 1 ), [Ni(3-bpah)(1,4-BDC)(H 2 O) 3 ] ( 2 ), [Cu(3-bpah)(1,4-BDC)] ( 3 ), [Zn(3-bpah)(1,4-BDC)]H 2 O ( 4 ) and [Cd(3-bpah)(1,4-BDC)(H 2 O)] ( 5 ), have been hydrothermally synthesized and structurally characterized. Complexes 1 and 2 are isostructural and display the similar 1D infinite chains, which are further linked via hydrogen-bonding interactions to generate 3D supramolecular frameworks. Complex 3 features a 3D polymeric framework with CdSO 4 -like topology. Complexes 4 and 5 show two similar 2D (2,4)-connected networks with (48 5 )(4) topology, in which the 3-bpah ligands adopt different 2 -bridging coordination modes via the ligation of two pyridyl nitrogen atoms in 4 and via the ligation of one pyridyl nitrogen and one amide oxygen atom in 5 . In addition, the central metals show different coordination geometries in 4 and 5 . The adjacent layers of complexes 4 and 5 are finally extended into 3D supramolecular architectures through hydrogen-bonding interactions. The effects of the central metals on the structures and properties of complexes 15 have been discussed. The electrochemical properties of complexes 13 and fluorescent sensing behaviors of 45 toward ethanol and nitrobenzene have been investigated in detail.
doi10.1039/c4dt00064a
pages8072-8082
date2014-05-06