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( E )-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases

An unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and... Full description

Journal Title: Chemical Communications 2015, Vol.51(36), pp.7729-7732
Main Author: Yao, Chuan-Zhi
Other Authors: Li, Qiang-Qiang , Wang, Mei-Mei , Ning, Xiao-Shan , Kang, Yan-Biao
Format: Electronic Article Electronic Article
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ID: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c5cc01965f
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recordid: rscc5cc01965f
title: ( E )-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases
format: Article
creator:
  • Yao, Chuan-Zhi
  • Li, Qiang-Qiang
  • Wang, Mei-Mei
  • Ning, Xiao-Shan
  • Kang, Yan-Biao
subjects:
  • Terminals
  • Aromatic Compounds
  • Alcohols
  • Sulfones
  • Reducing Agents
  • Hydrides
  • Olefins
  • Aldehydes
  • Miscellaneous Sciences (So)
  • Chemical and Electrochemical Properties (MD)
  • Chemical and Electrochemical Properties (Ep)
  • Chemical and Electrochemical Properties (Ed)
  • Chemical and Electrochemical Properties (EC)
ispartof: Chemical Communications, 2015, Vol.51(36), pp.7729-7732
description: An unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly ( E )-selective internal olefins.
language:
source:
identifier: ISSN: 1359-7345 ; E-ISSN: 1364-548X ; DOI: 10.1039/c5cc01965f
fulltext: fulltext
issn:
  • 1359-7345
  • 1364-548X
  • 1364548X
  • 13597345
url: Link


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title( E )-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases
creatorYao, Chuan-Zhi ; Li, Qiang-Qiang ; Wang, Mei-Mei ; Ning, Xiao-Shan ; Kang, Yan-Biao
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descriptionAn unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly ( E )-selective internal olefins.
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subjectTerminals ; Aromatic Compounds ; Alcohols ; Sulfones ; Reducing Agents ; Hydrides ; Olefins ; Aldehydes ; Miscellaneous Sciences (So) ; Chemical and Electrochemical Properties (MD) ; Chemical and Electrochemical Properties (Ep) ; Chemical and Electrochemical Properties (Ed) ; Chemical and Electrochemical Properties (EC);
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title( E )-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases
descriptionAn unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly ( E )-selective internal olefins.
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title( E )-Specific direct Julia-olefination of aryl alcohols without extra reducing agents promoted by bases
authorYao, Chuan-Zhi ; Li, Qiang-Qiang ; Wang, Mei-Mei ; Ning, Xiao-Shan ; Kang, Yan-Biao
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abstractAn unprecedented base-promoted direct olefination of aryl alcohols with sulfones via a Julia-type reaction has been described. No extra reductants are needed for Julia reaction since alcohols work as double sources of aldehydes and the hydride. Generally high yields were given for both terminal and highly ( E )-selective internal olefins.
doi10.1039/c5cc01965f
pages7729-7732
date2015-04-21