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Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

A metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N , N , N -trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereosel... Full description

Journal Title: Green Chemistry 2017, Vol.19(9), pp.2076-2079
Main Author: Liu, Liyan
Other Authors: Wang, Zhiyong
Format: Electronic Article Electronic Article
Language:
Subjects:
ID: ISSN: 1463-9262 ; E-ISSN: 1463-9270 ; DOI: 10.1039/c7gc00212b
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recordid: rscc7gc00212b
title: Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water
format: Article
creator:
  • Liu, Liyan
  • Wang, Zhiyong
subjects:
  • Iodides
  • Alkenes
  • Carboxylic Acids
  • Heterocyclic Aromatic Compounds
  • Synthesis
  • Chemical and Electrochemical Properties (MD)
  • Chemical and Electrochemical Properties (Ep)
  • Chemical and Electrochemical Properties (Ed)
  • Chemical and Electrochemical Properties (EC)
ispartof: Green Chemistry, 2017, Vol.19(9), pp.2076-2079
description: A metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N , N , N -trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.
language:
source:
identifier: ISSN: 1463-9262 ; E-ISSN: 1463-9270 ; DOI: 10.1039/c7gc00212b
fulltext: no_fulltext
issn:
  • 1463-9262
  • 1463-9270
  • 14639270
  • 14639262
url: Link


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descriptionA metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N , N , N -trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.
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subjectIodides ; Alkenes ; Carboxylic Acids ; Heterocyclic Aromatic Compounds ; Synthesis ; Chemical and Electrochemical Properties (MD) ; Chemical and Electrochemical Properties (Ep) ; Chemical and Electrochemical Properties (Ed) ; Chemical and Electrochemical Properties (EC);
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titleMetal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water
descriptionA metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N , N , N -trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.
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titleMetal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water
authorLiu, Liyan ; Wang, Zhiyong
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abstractA metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N , N , N -trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.
doi10.1039/c7gc00212b
pages2076-2079
date2017-05-08