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Asymmetric fluorination of indanone-2-carboxylates using a polystyrene-supported diphenylamine-linked bis(oxazoline) complex

A highly enantioselective fluorination of indanone-2-carboxylates catalyzed by a polystyrene-supported diphenylamine-linked bis(oxazoline) (PS-box)-Cu(OTf) 2 complex has been developed in a continuous flow system. The supported complex exhibited extremely efficient catalytic performance with high ac... Full description

Journal Title: Organic & Biomolecular Chemistry 2018, Vol.16(41), pp.7702-7710
Main Author: Wang, Biao
Other Authors: Wang, Yifeng , Jiang, Yidong , Chu, Mingming , Qi, Suosuo , Ju, Wanzhen , Xu, Danqian
Format: Electronic Article Electronic Article
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Subjects:
ID: ISSN: 1477-0520 ; E-ISSN: 1477-0539 ; DOI: 10.1039/c8ob01943f
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recordid: rscc8ob01943f
title: Asymmetric fluorination of indanone-2-carboxylates using a polystyrene-supported diphenylamine-linked bis(oxazoline) complex
format: Article
creator:
  • Wang, Biao
  • Wang, Yifeng
  • Jiang, Yidong
  • Chu, Mingming
  • Qi, Suosuo
  • Ju, Wanzhen
  • Xu, Danqian
subjects:
  • Enantiomers
  • Catalysis
  • Enantiomers
  • Flow System
  • Polystyrene
  • Polystyrene Resins
  • Carboxylates
  • Fluorination
  • Continuous Flow
  • Continuous Flow
ispartof: Organic & Biomolecular Chemistry, 2018, Vol.16(41), pp.7702-7710
description: A highly enantioselective fluorination of indanone-2-carboxylates catalyzed by a polystyrene-supported diphenylamine-linked bis(oxazoline) (PS-box)-Cu(OTf) 2 complex has been developed in a continuous flow system. The supported complex exhibited extremely efficient catalytic performance with high activity, affording the corresponding products in excellent yields (up to 99% yield) with excellent enantioselectivities (up to 99% ee) and more than 4000 turnover number (TON).
language:
source:
identifier: ISSN: 1477-0520 ; E-ISSN: 1477-0539 ; DOI: 10.1039/c8ob01943f
fulltext: no_fulltext
issn:
  • 1477-0520
  • 1477-0539
  • 14770539
  • 14770520
url: Link


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titleAsymmetric fluorination of indanone-2-carboxylates using a polystyrene-supported diphenylamine-linked bis(oxazoline) complex
creatorWang, Biao ; Wang, Yifeng ; Jiang, Yidong ; Chu, Mingming ; Qi, Suosuo ; Ju, Wanzhen ; Xu, Danqian
ispartofOrganic & Biomolecular Chemistry, 2018, Vol.16(41), pp.7702-7710
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descriptionA highly enantioselective fluorination of indanone-2-carboxylates catalyzed by a polystyrene-supported diphenylamine-linked bis(oxazoline) (PS-box)-Cu(OTf) 2 complex has been developed in a continuous flow system. The supported complex exhibited extremely efficient catalytic performance with high activity, affording the corresponding products in excellent yields (up to 99% yield) with excellent enantioselectivities (up to 99% ee) and more than 4000 turnover number (TON).
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subjectEnantiomers ; Catalysis ; Enantiomers ; Flow System ; Polystyrene ; Polystyrene Resins ; Carboxylates ; Fluorination ; Continuous Flow ; Continuous Flow;
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titleAsymmetric fluorination of indanone-2-carboxylates using a polystyrene-supported diphenylamine-linked bis(oxazoline) complex
descriptionA highly enantioselective fluorination of indanone-2-carboxylates catalyzed by a polystyrene-supported diphenylamine-linked bis(oxazoline) (PS-box)-Cu(OTf) 2 complex has been developed in a continuous flow system. The supported complex exhibited extremely efficient catalytic performance with high activity, affording the corresponding products in excellent yields (up to 99% yield) with excellent enantioselectivities (up to 99% ee) and more than 4000 turnover number (TON).
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atitleAsymmetric fluorination of indanone-2-carboxylates using a polystyrene-supported diphenylamine-linked bis(oxazoline) complex
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abstractA highly enantioselective fluorination of indanone-2-carboxylates catalyzed by a polystyrene-supported diphenylamine-linked bis(oxazoline) (PS-box)-Cu(OTf) 2 complex has been developed in a continuous flow system. The supported complex exhibited extremely efficient catalytic performance with high activity, affording the corresponding products in excellent yields (up to 99% yield) with excellent enantioselectivities (up to 99% ee) and more than 4000 turnover number (TON).
doi10.1039/c8ob01943f
pages7702-7710
date2018-10-24