schliessen

Filtern

 

Bibliotheken

Enhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors

We prepared the diastereoisomers of BINOL based bisboronic acid chiral probes (the probes are with dual chirogenic centers) for enantioselective recognition of chiral analytes, such as tartaric acids, D-sorbitol, etc. We found the diastereoisomeric probes give different emission intensity-pH profile... Full description

Journal Title: Journal of Fluorescence 2011, Vol.21(6), pp.2077-2084
Main Author: Li, Qiuting
Other Authors: Guo, Huimin , Wu, Yubo , Zhang, Xin , Liu, Yifan , Zhao, Jianzhang
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 1053-0509 ; E-ISSN: 1573-4994 ; DOI: 10.1007/s10895-011-0906-3
Link: http://dx.doi.org/10.1007/s10895-011-0906-3
Zum Text:
SendSend as email Add to Book BagAdd to Book Bag
Staff View
recordid: springer_jour10.1007/s10895-011-0906-3
title: Enhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors
format: Article
creator:
  • Li, Qiuting
  • Guo, Huimin
  • Wu, Yubo
  • Zhang, Xin
  • Liu, Yifan
  • Zhao, Jianzhang
subjects:
  • Boronic acid
  • Chiral fluorescent chemosensors
  • BINOL
ispartof: Journal of Fluorescence, 2011, Vol.21(6), pp.2077-2084
description: We prepared the diastereoisomers of BINOL based bisboronic acid chiral probes (the probes are with dual chirogenic centers) for enantioselective recognition of chiral analytes, such as tartaric acids, D-sorbitol, etc. We found the diastereoisomeric probes give different emission intensity-pH profiles, a phenomenon was reported, probably, for the first time. We found that with the second chirogenic center, the selectivity of the probes toward chiral analytes can be improved. For example, the diastereoisomeric probes give drastically different response to D-sorbitol, the same selectivity was not found for the BINOL bisboronic acid probes with single chirogenic center. Our result with the diastereoisomeric probes is helpful for design of new chiral molecular probes to enhance the selectivity of the boronic acid sensors toward chiral analytes.
language: eng
source:
identifier: ISSN: 1053-0509 ; E-ISSN: 1573-4994 ; DOI: 10.1007/s10895-011-0906-3
fulltext: fulltext
issn:
  • 1573-4994
  • 15734994
  • 1053-0509
  • 10530509
url: Link


@attributes
ID136633506
RANK0.07
NO1
SEARCH_ENGINEprimo_central_multiple_fe
SEARCH_ENGINE_TYPEPrimo Central Search Engine
LOCALfalse
PrimoNMBib
record
control
sourcerecordid10.1007/s10895-011-0906-3
sourceidspringer_jour
recordidTN_springer_jour10.1007/s10895-011-0906-3
sourcesystemPC
pqid902087704
display
typearticle
titleEnhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors
creatorLi, Qiuting ; Guo, Huimin ; Wu, Yubo ; Zhang, Xin ; Liu, Yifan ; Zhao, Jianzhang
ispartofJournal of Fluorescence, 2011, Vol.21(6), pp.2077-2084
identifier
subjectBoronic acid ; Chiral fluorescent chemosensors ; BINOL
descriptionWe prepared the diastereoisomers of BINOL based bisboronic acid chiral probes (the probes are with dual chirogenic centers) for enantioselective recognition of chiral analytes, such as tartaric acids, D-sorbitol, etc. We found the diastereoisomeric probes give different emission intensity-pH profiles, a phenomenon was reported, probably, for the first time. We found that with the second chirogenic center, the selectivity of the probes toward chiral analytes can be improved. For example, the diastereoisomeric probes give drastically different response to D-sorbitol, the same selectivity was not found for the BINOL bisboronic acid probes with single chirogenic center. Our result with the diastereoisomeric probes is helpful for design of new chiral molecular probes to enhance the selectivity of the boronic acid sensors toward chiral analytes.
languageeng
source
version4
lds50peer_reviewed
links
openurl$$Topenurl_article
openurlfulltext$$Topenurlfull_article
backlink$$Uhttp://dx.doi.org/10.1007/s10895-011-0906-3$$EView_full_text_in_Springer_(Subscribers_only)
search
creatorcontrib
0Li, Qiuting
1Guo, Huimin
2Wu, Yubo
3Zhang, Xin
4Liu, Yifan
5Zhao, Jianzhang
titleEnhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors
descriptionWe prepared the diastereoisomers of BINOL based bisboronic acid chiral probes (the probes are with dual chirogenic centers) for enantioselective recognition of chiral analytes, such as tartaric acids, D-sorbitol, etc. We found the diastereoisomeric probes give different emission intensity-pH profiles, a phenomenon was reported, probably, for the first time. We found that with the second chirogenic center, the selectivity of the probes toward chiral analytes can be improved. For example, the diastereoisomeric probes give drastically different response to D-sorbitol, the same selectivity was not found for the BINOL bisboronic acid probes with single chirogenic center. Our result with the diastereoisomeric probes is helpful for design of new chiral molecular probes to enhance the selectivity of the boronic acid sensors toward chiral analytes.
subject
0Boronic acid
1Chiral fluorescent chemosensors
2BINOL
general
010.1007/s10895-011-0906-3
1English
2Springer Science & Business Media B.V.
3SpringerLink
sourceidspringer_jour
recordidspringer_jour10.1007/s10895-011-0906-3
issn
01573-4994
115734994
21053-0509
310530509
rsrctypearticle
creationdate2011
addtitle
0Journal of Fluorescence
1J Fluoresc
searchscopespringer_journals_complete
scopespringer_journals_complete
lsr30VSR-Enriched:[pages, pqid]
sort
titleEnhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors
authorLi, Qiuting ; Guo, Huimin ; Wu, Yubo ; Zhang, Xin ; Liu, Yifan ; Zhao, Jianzhang
creationdate20111100
facets
frbrgroupid8097008965688704292
frbrtype5
languageeng
creationdate2011
topic
0Boronic Acid
1Chiral Fluorescent Chemosensors
2Binol
collectionSpringerLink
prefilterarticles
rsrctypearticles
creatorcontrib
0Li, Qiuting
1Guo, Huimin
2Wu, Yubo
3Zhang, Xin
4Liu, Yifan
5Zhao, Jianzhang
jtitleJournal Of Fluorescence
toplevelpeer_reviewed
delivery
delcategoryRemote Search Resource
fulltextfulltext
addata
aulast
0Li
1Guo
2Wu
3Zhang
4Liu
5Zhao
aufirst
0Qiuting
1Huimin
2Yubo
3Xin
4Yifan
5Jianzhang
au
0Li, Qiuting
1Guo, Huimin
2Wu, Yubo
3Zhang, Xin
4Liu, Yifan
5Zhao, Jianzhang
atitleEnhanced Enantioselective Recognition with Diastereoisomeric BINOL Based Chiral Fluorescent Boronic Acid Sensors
jtitleJournal of Fluorescence
stitleJ Fluoresc
risdate201111
volume21
issue6
spage2077
epage2084
issn1053-0509
eissn1573-4994
genrearticle
ristypeJOUR
abstractWe prepared the diastereoisomers of BINOL based bisboronic acid chiral probes (the probes are with dual chirogenic centers) for enantioselective recognition of chiral analytes, such as tartaric acids, D-sorbitol, etc. We found the diastereoisomeric probes give different emission intensity-pH profiles, a phenomenon was reported, probably, for the first time. We found that with the second chirogenic center, the selectivity of the probes toward chiral analytes can be improved. For example, the diastereoisomeric probes give drastically different response to D-sorbitol, the same selectivity was not found for the BINOL bisboronic acid probes with single chirogenic center. Our result with the diastereoisomeric probes is helpful for design of new chiral molecular probes to enhance the selectivity of the boronic acid sensors toward chiral analytes.
copBoston
pubSpringer US
doi10.1007/s10895-011-0906-3
pages2077-2084
date2011-11