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Sheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene with Molecular Oxygen

The sheet polymrtic iron (III) porphyrin complex [PFe (III)TPP] was prepared and charactrtized by FT-IR, TG-DTA and DTG, SEM and XPS. It was applied to catalytic oxidation of styrene with molecular oxygen and exhibited excellent catalytic activity. The results showed that the conversion reached to 5... Full description

Journal Title: Applied Mechanics and Materials 2014, Vol.496, pp.88-91
Main Author: Li, Xido Dong
Other Authors: Wang, Xiao Feng , Zhu, Yuan Cheng , An, Mei Mei
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 1660-9336 ; E-ISSN: 1662-7482 ; DOI: 10.4028/www.scientific.net/AMM.496-500.88
Link: http://www.scientific.net/AMM.496-500.88
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recordid: transtech10.4028/www.scientific.net/AMM.496-500.88
title: Sheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene with Molecular Oxygen
format: Article
creator:
  • Li, Xido Dong
  • Wang, Xiao Feng
  • Zhu, Yuan Cheng
  • An, Mei Mei
subjects:
  • Styrenes
  • Porphyrins
  • X-Ray Photoelectron Spectroscopy
  • Oxidation
  • Conversion
  • Catalysts
  • Iron
  • Catalysis
  • Theoretical Mechanics and Dynamics (Mt)
  • General and Nonclassified (MD)
  • General and Nonclassified (Ep)
  • General and Nonclassified (Ed)
  • General and Nonclassified (EC)
  • Theoretical Mechanics and Dynamics (CE)
  • Catalytic Oxidation
  • Molecular Oxygen
  • Pfe(III) Tpp Complex
  • Styrene
ispartof: Applied Mechanics and Materials, 2014, Vol.496, pp.88-91
description: The sheet polymrtic iron (III) porphyrin complex [PFe (III)TPP] was prepared and charactrtized by FT-IR, TG-DTA and DTG, SEM and XPS. It was applied to catalytic oxidation of styrene with molecular oxygen and exhibited excellent catalytic activity. The results showed that the conversion reached to 50.5% in mild concitions, the major products of benzaldhyde (65.2% at 90°C) were obtained, and the catalyst could be efficiently reused five times.
language: eng
source:
identifier: ISSN: 1660-9336 ; E-ISSN: 1662-7482 ; DOI: 10.4028/www.scientific.net/AMM.496-500.88
fulltext: fulltext
issn:
  • 1660-9336
  • 1662-7482
  • 16609336
  • 16627482
url: Link


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titleSheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene with Molecular Oxygen
creatorLi, Xido Dong ; Wang, Xiao Feng ; Zhu, Yuan Cheng ; An, Mei Mei
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descriptionThe sheet polymrtic iron (III) porphyrin complex [PFe (III)TPP] was prepared and charactrtized by FT-IR, TG-DTA and DTG, SEM and XPS. It was applied to catalytic oxidation of styrene with molecular oxygen and exhibited excellent catalytic activity. The results showed that the conversion reached to 50.5% in mild concitions, the major products of benzaldhyde (65.2% at 90°C) were obtained, and the catalyst could be efficiently reused five times.
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subjectStyrenes ; Porphyrins ; X-Ray Photoelectron Spectroscopy ; Oxidation ; Conversion ; Catalysts ; Iron ; Catalysis ; Theoretical Mechanics and Dynamics (Mt) ; General and Nonclassified (MD) ; General and Nonclassified (Ep) ; General and Nonclassified (Ed) ; General and Nonclassified (EC) ; Theoretical Mechanics and Dynamics (CE) ; Catalytic Oxidation ; Molecular Oxygen ; Pfe(III) Tpp Complex ; Styrene;
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titleSheet Polymeric Iron (III) Porphyrin Complexes Catalytic Oxidation of Styrene with Molecular Oxygen
descriptionThe sheet polymrtic iron (III) porphyrin complex [PFe (III)TPP] was prepared and charactrtized by FT-IR, TG-DTA and DTG, SEM and XPS. It was applied to catalytic oxidation of styrene with molecular oxygen and exhibited excellent catalytic activity. The results showed that the conversion reached to 50.5% in mild concitions, the major products of benzaldhyde (65.2% at 90°C) were obtained, and the catalyst could be efficiently reused five times.
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abstractThe sheet polymrtic iron (III) porphyrin complex [PFe (III)TPP] was prepared and charactrtized by FT-IR, TG-DTA and DTG, SEM and XPS. It was applied to catalytic oxidation of styrene with molecular oxygen and exhibited excellent catalytic activity. The results showed that the conversion reached to 50.5% in mild concitions, the major products of benzaldhyde (65.2% at 90°C) were obtained, and the catalyst could be efficiently reused five times.
pubTrans Tech Publications
doi10.4028/www.scientific.net/AMM.496-500.88
issueFrontiers of Manufacturing and Design Science IV
pages88-91
isbn9783037859926
date2014-04-16