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Palladium‐Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters

Carbonylation reactions represent useful tools for organic synthesis. However, the necessity to use gaseous carbon monoxide is a disadvantage for most organic chemists. To solve this problem, novel protocols have been developed for conducting palladium‐catalyzed reductive carbonylations of aryl brom... Full description

Journal Title: Angewandte Chemie 15 September 2014, Vol.126(38), pp.10254-10258
Main Author: Natte, Kishore
Other Authors: Dumrath, Andreas , Neumann, Helfried , Beller, Matthias
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0044-8249 ; E-ISSN: 1521-3757 ; DOI: 10.1002/ange.201404833
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recordid: wj10.1002/ange.201404833
title: Palladium‐Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters
format: Article
creator:
  • Natte, Kishore
  • Dumrath, Andreas
  • Neumann, Helfried
  • Beller, Matthias
subjects:
  • Arene
  • Carbonylierungen
  • Palladium
  • Reaktionsmechanismen
  • Synthesemethoden
ispartof: Angewandte Chemie, 15 September 2014, Vol.126(38), pp.10254-10258
description: Carbonylation reactions represent useful tools for organic synthesis. However, the necessity to use gaseous carbon monoxide is a disadvantage for most organic chemists. To solve this problem, novel protocols have been developed for conducting palladium‐catalyzed reductive carbonylations of aryl bromides and alkoxycarbonylations using paraformaldehyde as an external CO source (CO gas free). Hence, aromatic aldehydes and esters were synthesized in moderate to good yields. : Neuartige Syntheseprotokolle für Palladium‐katalysierte reduktive Carbonylierungen und Alkoxycarbonylierungen von Arylbromiden mit Paraformaldehyd als externe CO‐Quelle wurden entwickelt. Der Vorteil: Auf die Verwendung von Kohlenmonoxidgas kann verzichtet werden.
language: eng
source:
identifier: ISSN: 0044-8249 ; E-ISSN: 1521-3757 ; DOI: 10.1002/ange.201404833
fulltext: fulltext
issn:
  • 0044-8249
  • 00448249
  • 1521-3757
  • 15213757
url: Link


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titlePalladium‐Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters
creatorNatte, Kishore ; Dumrath, Andreas ; Neumann, Helfried ; Beller, Matthias
ispartofAngewandte Chemie, 15 September 2014, Vol.126(38), pp.10254-10258
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subjectArene ; Carbonylierungen ; Palladium ; Reaktionsmechanismen ; Synthesemethoden
descriptionCarbonylation reactions represent useful tools for organic synthesis. However, the necessity to use gaseous carbon monoxide is a disadvantage for most organic chemists. To solve this problem, novel protocols have been developed for conducting palladium‐catalyzed reductive carbonylations of aryl bromides and alkoxycarbonylations using paraformaldehyde as an external CO source (CO gas free). Hence, aromatic aldehydes and esters were synthesized in moderate to good yields. : Neuartige Syntheseprotokolle für Palladium‐katalysierte reduktive Carbonylierungen und Alkoxycarbonylierungen von Arylbromiden mit Paraformaldehyd als externe CO‐Quelle wurden entwickelt. Der Vorteil: Auf die Verwendung von Kohlenmonoxidgas kann verzichtet werden.
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titlePalladium‐Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters
descriptionCarbonylation reactions represent useful tools for organic synthesis. However, the necessity to use gaseous carbon monoxide is a disadvantage for most organic chemists. To solve this problem, novel protocols have been developed for conducting palladium‐catalyzed reductive carbonylations of aryl bromides and alkoxycarbonylations using paraformaldehyde as an external CO source (CO gas free). Hence, aromatic aldehydes and esters were synthesized in moderate to good yields. : Neuartige Syntheseprotokolle für Palladium‐katalysierte reduktive Carbonylierungen und Alkoxycarbonylierungen von Arylbromiden mit Paraformaldehyd als externe CO‐Quelle wurden entwickelt. Der Vorteil: Auf die Verwendung von Kohlenmonoxidgas kann verzichtet werden.
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titlePalladium‐Catalyzed Carbonylations of Aryl Bromides using Paraformaldehyde: Synthesis of Aldehydes and Esters
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abstractCarbonylation reactions represent useful tools for organic synthesis. However, the necessity to use gaseous carbon monoxide is a disadvantage for most organic chemists. To solve this problem, novel protocols have been developed for conducting palladium‐catalyzed reductive carbonylations of aryl bromides and alkoxycarbonylations using paraformaldehyde as an external CO source (CO gas free). Hence, aromatic aldehydes and esters were synthesized in moderate to good yields. : Neuartige Syntheseprotokolle für Palladium‐katalysierte reduktive Carbonylierungen und Alkoxycarbonylierungen von Arylbromiden mit Paraformaldehyd als externe CO‐Quelle wurden entwickelt. Der Vorteil: Auf die Verwendung von Kohlenmonoxidgas kann verzichtet werden.
copWeinheim
pubWILEY‐VCH Verlag
doi10.1002/ange.201404833
pages10254-10258
date2014-09-15