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Hydration of Epoxides on [Co III (salen)] Encapsulated in Silica‐Based Nanoreactors

has its benefits in the case of a non‐acid solid catalyst prepared by encapsulating [Co(salen)] in the nanocages of mesoporous silica. The catalytic activity and selectivity of [Co(salen)] were increased significantly owing to the enhanced cooperative activation effect in the nanoreactors. Thus, eth... Full description

Journal Title: Angewandte Chemie International Edition 12 November 2012, Vol.51(46), pp.11517-11521
Main Author: Li, Bo
Other Authors: Bai, Shiyang , Wang, Xuefeng , Zhong, Mingmei , Yang, Qihua , Li, Can
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201203774
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recordid: wj10.1002/anie.201203774
title: Hydration of Epoxides on [Co III (salen)] Encapsulated in Silica‐Based Nanoreactors
format: Article
creator:
  • Li, Bo
  • Bai, Shiyang
  • Wang, Xuefeng
  • Zhong, Mingmei
  • Yang, Qihua
  • Li, Can
subjects:
  • Cobalt
  • Cooperative Activation
  • Epoxide Hydration
  • Green Chemistry
  • Nanoreactors
ispartof: Angewandte Chemie International Edition, 12 November 2012, Vol.51(46), pp.11517-11521
description: has its benefits in the case of a non‐acid solid catalyst prepared by encapsulating [Co(salen)] in the nanocages of mesoporous silica. The catalytic activity and selectivity of [Co(salen)] were increased significantly owing to the enhanced cooperative activation effect in the nanoreactors. Thus, ethylene oxide (EO) underwent hydration at a low 2:1 HO/EO molar ratio to give ethylene glycol in up to 96 % yield.
language: eng
source:
identifier: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201203774
fulltext: fulltext
issn:
  • 1433-7851
  • 14337851
  • 1521-3773
  • 15213773
url: Link


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titleHydration of Epoxides on [Co III (salen)] Encapsulated in Silica‐Based Nanoreactors
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subjectCobalt ; Cooperative Activation ; Epoxide Hydration ; Green Chemistry ; Nanoreactors
descriptionhas its benefits in the case of a non‐acid solid catalyst prepared by encapsulating [Co(salen)] in the nanocages of mesoporous silica. The catalytic activity and selectivity of [Co(salen)] were increased significantly owing to the enhanced cooperative activation effect in the nanoreactors. Thus, ethylene oxide (EO) underwent hydration at a low 2:1 HO/EO molar ratio to give ethylene glycol in up to 96 % yield.
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titleHydration of Epoxides on [Co III (salen)] Encapsulated in Silica‐Based Nanoreactors
descriptionhas its benefits in the case of a non‐acid solid catalyst prepared by encapsulating [Co(salen)] in the nanocages of mesoporous silica. The catalytic activity and selectivity of [Co(salen)] were increased significantly owing to the enhanced cooperative activation effect in the nanoreactors. Thus, ethylene oxide (EO) underwent hydration at a low 2:1 HO/EO molar ratio to give ethylene glycol in up to 96 % yield.
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abstracthas its benefits in the case of a non‐acid solid catalyst prepared by encapsulating [Co(salen)] in the nanocages of mesoporous silica. The catalytic activity and selectivity of [Co(salen)] were increased significantly owing to the enhanced cooperative activation effect in the nanoreactors. Thus, ethylene oxide (EO) underwent hydration at a low 2:1 HO/EO molar ratio to give ethylene glycol in up to 96 % yield.
copWeinheim
pubWILEY‐VCH Verlag
doi10.1002/anie.201203774
pages11517-21
date2012-11-12