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Missing Small‐Bandgap Metallofullerenes: Their Isolation and Electronic Properties

: In situ exohedral trifluoromethylation of endohedral fullerenes using an arc‐discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an ext... Full description

Journal Title: Angewandte Chemie International Edition 04 November 2013, Vol.52(45), pp.11770-11774
Main Author: Wang, Zhiyong
Other Authors: Nakanishi, Yusuke , Noda, Shoko , Niwa, Hiroyuki , Zhang, Jinying , Kitaura, Ryo , Shinohara, Hisanori
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201305573
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recordid: wj10.1002/anie.201305573
title: Missing Small‐Bandgap Metallofullerenes: Their Isolation and Electronic Properties
format: Article
creator:
  • Wang, Zhiyong
  • Nakanishi, Yusuke
  • Noda, Shoko
  • Niwa, Hiroyuki
  • Zhang, Jinying
  • Kitaura, Ryo
  • Shinohara, Hisanori
subjects:
  • Arc Discharge
  • Electronic Structures
  • Fullerenes
  • Trifluoromethylation
  • Yttrium
ispartof: Angewandte Chemie International Edition, 04 November 2013, Vol.52(45), pp.11770-11774
description: : In situ exohedral trifluoromethylation of endohedral fullerenes using an arc‐discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.
language: eng
source:
identifier: ISSN: 1433-7851 ; E-ISSN: 1521-3773 ; DOI: 10.1002/anie.201305573
fulltext: fulltext
issn:
  • 1433-7851
  • 14337851
  • 1521-3773
  • 15213773
url: Link


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description: In situ exohedral trifluoromethylation of endohedral fullerenes using an arc‐discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.
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titleMissing Small‐Bandgap Metallofullerenes: Their Isolation and Electronic Properties
description: In situ exohedral trifluoromethylation of endohedral fullerenes using an arc‐discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.
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abstract: In situ exohedral trifluoromethylation of endohedral fullerenes using an arc‐discharge method (see picture) gives access to a wide variety of missing unconventional metallofullerenes. Such otherwise insoluble and unstable metallofullerenes become soluble and stable in organic solvents after an exterior functionalization.
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pubWILEY‐VCH Verlag
doi10.1002/anie.201305573
pages11770-11774
date2013-11-04