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Structure evolution of ultra high molecular weight polyethylene/montmorillonite nanocomposite fibers prepared by melt spinning

Nanocomposite fibers of ultra high molecular weight polyethylene (UHMWPE) and organic montmorillonite (OMMT) were successfully prepared by a melt‐spinning process. The evolution of the microstructures of the nanocomposite fibers in the drawing process was preliminarily studied by X‐ray diffraction (... Full description

Journal Title: Journal of Applied Polymer Science 15 December 2013, Vol.130(6), pp.3930-3936
Main Author: Zhang, Qiang
Other Authors: Wang, Qingzhao , Chen, Yong
Format: Electronic Article Electronic Article
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ID: ISSN: 0021-8995 ; E-ISSN: 1097-4628 ; DOI: 10.1002/app.39676
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recordid: wj10.1002/app.39676
title: Structure evolution of ultra high molecular weight polyethylene/montmorillonite nanocomposite fibers prepared by melt spinning
format: Article
creator:
  • Zhang, Qiang
  • Wang, Qingzhao
  • Chen, Yong
subjects:
  • Structure–Property Relations
  • X‐Ray
  • Fibers
  • Differential Scanning Calorimetry Dsc
  • Crystallization
ispartof: Journal of Applied Polymer Science, 15 December 2013, Vol.130(6), pp.3930-3936
description: Nanocomposite fibers of ultra high molecular weight polyethylene (UHMWPE) and organic montmorillonite (OMMT) were successfully prepared by a melt‐spinning process. The evolution of the microstructures of the nanocomposite fibers in the drawing process was preliminarily studied by X‐ray diffraction (XRD), differential scanning calorimetry, and small‐angle X‐ray scatters. With the increase of draw ratio values, the crystallinity of the nanocomposite fibers increased, the grain size decreased, and the folded chain crystals gradually transformed into extended chain crystals. The results suggested the evolution of the nanocomposite fibers was similar with that of the fibers made by gel‐spun drawing process. The addition of OMMT in UHMWPE improved the fluidity of the composites yet without affecting the crystal structure of UHMWPE in the drawing process. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3930–3936, 2013
language:
source:
identifier: ISSN: 0021-8995 ; E-ISSN: 1097-4628 ; DOI: 10.1002/app.39676
fulltext: fulltext
issn:
  • 0021-8995
  • 00218995
  • 1097-4628
  • 10974628
url: Link


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titleStructure evolution of ultra high molecular weight polyethylene/montmorillonite nanocomposite fibers prepared by melt spinning
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subjectStructure–Property Relations ; X‐Ray ; Fibers ; Differential Scanning Calorimetry Dsc ; Crystallization
descriptionNanocomposite fibers of ultra high molecular weight polyethylene (UHMWPE) and organic montmorillonite (OMMT) were successfully prepared by a melt‐spinning process. The evolution of the microstructures of the nanocomposite fibers in the drawing process was preliminarily studied by X‐ray diffraction (XRD), differential scanning calorimetry, and small‐angle X‐ray scatters. With the increase of draw ratio values, the crystallinity of the nanocomposite fibers increased, the grain size decreased, and the folded chain crystals gradually transformed into extended chain crystals. The results suggested the evolution of the nanocomposite fibers was similar with that of the fibers made by gel‐spun drawing process. The addition of OMMT in UHMWPE improved the fluidity of the composites yet without affecting the crystal structure of UHMWPE in the drawing process. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3930–3936, 2013
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titleStructure evolution of ultra high molecular weight polyethylene/montmorillonite nanocomposite fibers prepared by melt spinning
descriptionNanocomposite fibers of ultra high molecular weight polyethylene (UHMWPE) and organic montmorillonite (OMMT) were successfully prepared by a melt‐spinning process. The evolution of the microstructures of the nanocomposite fibers in the drawing process was preliminarily studied by X‐ray diffraction (XRD), differential scanning calorimetry, and small‐angle X‐ray scatters. With the increase of draw ratio values, the crystallinity of the nanocomposite fibers increased, the grain size decreased, and the folded chain crystals gradually transformed into extended chain crystals. The results suggested the evolution of the nanocomposite fibers was similar with that of the fibers made by gel‐spun drawing process. The addition of OMMT in UHMWPE improved the fluidity of the composites yet without affecting the crystal structure of UHMWPE in the drawing process. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3930–3936, 2013
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abstractNanocomposite fibers of ultra high molecular weight polyethylene (UHMWPE) and organic montmorillonite (OMMT) were successfully prepared by a melt‐spinning process. The evolution of the microstructures of the nanocomposite fibers in the drawing process was preliminarily studied by X‐ray diffraction (XRD), differential scanning calorimetry, and small‐angle X‐ray scatters. With the increase of draw ratio values, the crystallinity of the nanocomposite fibers increased, the grain size decreased, and the folded chain crystals gradually transformed into extended chain crystals. The results suggested the evolution of the nanocomposite fibers was similar with that of the fibers made by gel‐spun drawing process. The addition of OMMT in UHMWPE improved the fluidity of the composites yet without affecting the crystal structure of UHMWPE in the drawing process. © 2013 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 130: 3930–3936, 2013
doi10.1002/app.39676
pages3930-3936
date2013-12-15