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NIS‐Catalyzed Reactions: Amidation of Acetophenones and Oxidative Amination of Propiophenones

: The ‐iodosuccinimide (NIS)‐catalyzed amidation of acetophenone derivatives by using butylhydroperoxide (TBHP) as an oxidant is presented. A variety of acetyl derivatives of heterocyclic compounds were easily converted to their corresponding ketoamides under these conditions. A new, NIS‐catalyzed a... Full description

Journal Title: Chemistry – A European Journal 12 November 2012, Vol.18(46), pp.14638-14642
Main Author: Lamani, Manjunath
Other Authors: Prabhu, Kandikere Ramaiah
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201202703
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recordid: wj10.1002/chem.201202703
title: NIS‐Catalyzed Reactions: Amidation of Acetophenones and Oxidative Amination of Propiophenones
format: Article
creator:
  • Lamani, Manjunath
  • Prabhu, Kandikere Ramaiah
subjects:
  • Acetophenones
  • Amination
  • Dehydrogenation
  • ‐Iodosuccinimide
  • Oxidation
  • Propiophenones
ispartof: Chemistry – A European Journal, 12 November 2012, Vol.18(46), pp.14638-14642
description: : The ‐iodosuccinimide (NIS)‐catalyzed amidation of acetophenone derivatives by using butylhydroperoxide (TBHP) as an oxidant is presented. A variety of acetyl derivatives of heterocyclic compounds were easily converted to their corresponding ketoamides under these conditions. A new, NIS‐catalyzed amination of propiophenone and its derivatives in the presence of TBHP to furnish the corresponding 2‐aminoketone derivatives is the first reported single‐step amination of propiophenone derivatives.
language: eng
source:
identifier: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201202703
fulltext: fulltext
issn:
  • 0947-6539
  • 09476539
  • 1521-3765
  • 15213765
url: Link


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titleNIS‐Catalyzed Reactions: Amidation of Acetophenones and Oxidative Amination of Propiophenones
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ispartofChemistry – A European Journal, 12 November 2012, Vol.18(46), pp.14638-14642
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subjectAcetophenones ; Amination ; Dehydrogenation ; ‐Iodosuccinimide ; Oxidation ; Propiophenones
description: The ‐iodosuccinimide (NIS)‐catalyzed amidation of acetophenone derivatives by using butylhydroperoxide (TBHP) as an oxidant is presented. A variety of acetyl derivatives of heterocyclic compounds were easily converted to their corresponding ketoamides under these conditions. A new, NIS‐catalyzed amination of propiophenone and its derivatives in the presence of TBHP to furnish the corresponding 2‐aminoketone derivatives is the first reported single‐step amination of propiophenone derivatives.
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titleNIS‐Catalyzed Reactions: Amidation of Acetophenones and Oxidative Amination of Propiophenones
description: The ‐iodosuccinimide (NIS)‐catalyzed amidation of acetophenone derivatives by using butylhydroperoxide (TBHP) as an oxidant is presented. A variety of acetyl derivatives of heterocyclic compounds were easily converted to their corresponding ketoamides under these conditions. A new, NIS‐catalyzed amination of propiophenone and its derivatives in the presence of TBHP to furnish the corresponding 2‐aminoketone derivatives is the first reported single‐step amination of propiophenone derivatives.
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abstract: The ‐iodosuccinimide (NIS)‐catalyzed amidation of acetophenone derivatives by using butylhydroperoxide (TBHP) as an oxidant is presented. A variety of acetyl derivatives of heterocyclic compounds were easily converted to their corresponding ketoamides under these conditions. A new, NIS‐catalyzed amination of propiophenone and its derivatives in the presence of TBHP to furnish the corresponding 2‐aminoketone derivatives is the first reported single‐step amination of propiophenone derivatives.
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pubWILEY‐VCH Verlag
doi10.1002/chem.201202703
pages14638-42
date2012-11-12