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Electrochemical Synthesis of the Aryl α‐Ketoesters from Acetophenones Mediated by KI

: The oxidative coupling reaction of acetophenones with alcohol was developed by a dioxygen activation to afford α‐ketoesters under electrochemical conditions. This novel transformation not only provides a simple and efficient approach to synthetize α‐ketoester derivatives, but also invents a new st... Full description

Journal Title: Chemistry – A European Journal 23 December 2013, Vol.19(52), pp.17711-17714
Main Author: Zhang, Zhenlei
Other Authors: Su, Jihu , Zha, Zhenggen , Wang, Zhiyong
Format: Electronic Article Electronic Article
Language: English
Subjects:
ID: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201302307
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recordid: wj10.1002/chem.201302307
title: Electrochemical Synthesis of the Aryl α‐Ketoesters from Acetophenones Mediated by KI
format: Article
creator:
  • Zhang, Zhenlei
  • Su, Jihu
  • Zha, Zhenggen
  • Wang, Zhiyong
subjects:
  • Bond‐Forming Reactions
  • Electrochemistry Oxidation
  • Esterification
  • Iodine Radical
  • Oxygen
ispartof: Chemistry – A European Journal, 23 December 2013, Vol.19(52), pp.17711-17714
description: : The oxidative coupling reaction of acetophenones with alcohol was developed by a dioxygen activation to afford α‐ketoesters under electrochemical conditions. This novel transformation not only provides a simple and efficient approach to synthetize α‐ketoester derivatives, but also invents a new strategy to construct a CO bond by virtue of an anode oxidation (see scheme).
language: eng
source:
identifier: ISSN: 0947-6539 ; E-ISSN: 1521-3765 ; DOI: 10.1002/chem.201302307
fulltext: fulltext
issn:
  • 0947-6539
  • 09476539
  • 1521-3765
  • 15213765
url: Link


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titleElectrochemical Synthesis of the Aryl α‐Ketoesters from Acetophenones Mediated by KI
creatorZhang, Zhenlei ; Su, Jihu ; Zha, Zhenggen ; Wang, Zhiyong
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subjectBond‐Forming Reactions ; Electrochemistry Oxidation ; Esterification ; Iodine Radical ; Oxygen
description: The oxidative coupling reaction of acetophenones with alcohol was developed by a dioxygen activation to afford α‐ketoesters under electrochemical conditions. This novel transformation not only provides a simple and efficient approach to synthetize α‐ketoester derivatives, but also invents a new strategy to construct a CO bond by virtue of an anode oxidation (see scheme).
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titleElectrochemical Synthesis of the Aryl α‐Ketoesters from Acetophenones Mediated by KI
description: The oxidative coupling reaction of acetophenones with alcohol was developed by a dioxygen activation to afford α‐ketoesters under electrochemical conditions. This novel transformation not only provides a simple and efficient approach to synthetize α‐ketoester derivatives, but also invents a new strategy to construct a CO bond by virtue of an anode oxidation (see scheme).
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abstract: The oxidative coupling reaction of acetophenones with alcohol was developed by a dioxygen activation to afford α‐ketoesters under electrochemical conditions. This novel transformation not only provides a simple and efficient approach to synthetize α‐ketoester derivatives, but also invents a new strategy to construct a CO bond by virtue of an anode oxidation (see scheme).
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doi10.1002/chem.201302307
pages17711-17714
date2013-12-23